Porapak ist ein poröses Polymermaterial, welches in der Gaschromatographie eingesetzt wird. Das Material ist neben dem Bulk auch in bereits gepackten Säulen verfügbar. Durch die poröse Struktur, kann dieses Material für die Analyse von flüchtigen Verbindungen und leicht siedenden Lösungsmittel verwendet werden.
1mx2.3mm ID SUS column, 80/100 mesh, 30°C, 25ml/min He
Compounds | Porapak P | Porapak Q | Porapak R | Porapak S | Porapak N | Porapak T |
Oxygen | 0.23 | 0.24 | 0.24 | 0.24 | 0.24 | 0.24 |
Nitrogen | 0.23 | 0.24 | 0.24 | 0.24 | 0.24 | 0.24 |
Argon | 0.23 | 0.24 | 0.24 | 0.24 | 0.24 | 0.24 |
Carbonmonooxide | 0.23 | 0.24 | 0.27 | 0.24 | 0.24 | 0.24 |
Carbon dioxide | 0.36 | 0.65 | 0.60 | 0.66 | 0.90 | 1.26 |
Carbonyl sulfide | 1.15 | 3.33 | 2.83 | 3.47 | 4.05 | 4.71 |
Sulfur dioxide | 2.52 | 5.87 | 10.84 | 23.80 | 16.50 | 22.48 |
Nitric oxide (NO) | 0.27 | 0.30 | 0.28 | 0.26 | 0.28 | 0.28 |
Nitrous oxide (N2O) | 0.42 | 0.76 | 0.66 | 0.81 | 0.94 | 1.22 |
Methane | 0.26 | 0.35 | 0.32 | 0.38 | 0.35 | 0.39 |
Ethylene | 0.45 | 1.15 | 0.90 | 1.01 | 1.22 | 1.32 |
Acethylene | 0.53 | 1.15 | 1.16 | 1.20 | 2.00 | 2.96 |
Ethane | 0.54 | 1.60 | 1.16 | 1.36 | 1.50 | 1.54 |
Propylene | 1.40 | 6.44 | 4.43 | 5.39 | 7.14 | 7.28 |
Propane | 1.40 | 7.24 | 5.00 | 5.98 | 7.14 | 7.28 |
Ammonia | 0.65 | 1.52 | 1.88 | 1.77 | 1.89 | 2.72 |
Ethylene oxide | 4.45 | 12.70 | 12.51 | 14.82 | 24.78 | 34.05 |
Difluoroethane | 1.16 | 3.90 | 3.97 | 4.63 | 9.00 | 11.92 |
Chlorodifluoromethane(Freon 22) | 1.22 | 4.32 | 5.61 | 5.60 | 10.99 | 13.88 |
Methyl chloride | 2.10 | 6.16 | 5.74 | 7.00 | 9.76 | 11.92 |
Dichlorodifluoromethane(Freon 12) | 1.43 | 7.43 | 5.73 | 7.13 | 9.78 | 10.28 |
Chlorodifluoroethane | 2.04 | 15.44 | 11.71 | 13.73 | - | - |
Dichlorotetrafluoroethane | 10.40 | 25.75 | 19.51 | 20.32 | - | - |
1mx2.3mm ID SUS column, 80/100 mesh, 175°C, 25mL/min N2, FID
Gruppe | Verbindung | Porapak P | Porapak Q | Porapak R | Porapak S | Porapak N | Porapak T |
Säuren | Acetic acid | 0.39 | 1.08 | 2.14 | 3.68 | 4.18 | 5.21 |
Propionic acid | 0.65 | 2.42 | 4.75 | 9.05 | 9.11 | 10.68 | |
iso-Butyric acid | 0.91 | 4.43 | 8.28 | 16.41 | 16.32 | 18.13 | |
Butyric acid | 1.05 | 5.22 | 9.87 | 19.71 | 19.80 | 22.30 | |
iso-Valeric acid | 1.52 | 9.69 | 16.85 | 36.81 | 36.79 | 39.50 | |
Valeric acid | 1.89 | 12.12 | 21.70 | 45.70 | 45.30 | 48.90 | |
Alkohole | Methanol | 0.24 | 0.35 | 0.39 | 0.48 | 0.61 | 0.69 |
Ethanol | 0.30 | 0.60 | 0.63 | 0.76 | 1.21 | 1.20 | |
iso-Propanol | 0.37 | 0.91 | 0.89 | 1.03 | 1.79 | 1.90 | |
tert-Butanol | 0.38 | 1.40 | 1.35 | 1.69 | 2.56 | 2.67 | |
n-Propanol | 0.43 | 1.22 | 1.24 | 1.53 | 2.52 | 2.60 | |
sec-Butanol | 0.50 | 1.93 | 1.85 | 2.40 | 3.69 | 3.81 | |
iso-Butanol | 0.61 | 2.18 | 2.16 | 2.72 | 4.63 | 4.74 | |
tert-Pentanol | 0.62 | 3.17 | 2.90 | 3.78 | 5.87 | 5.84 | |
n-Butanol | 0.69 | 2.58 | 2.68 | 3.39 | 5.78 | 5.74 | |
iso-Pentanol | 1.07 | 4.87 | 4.75 | 6.14 | 10.82 | 10.76 | |
n-Pentano | 1.10 | 5.63 | 5.67 | 7.04 | 12.88 | 12.40 | |
Aldehyde | Acetaldehyde | 0.24 | 0.44 | 0.39 | 0.49 | 0.65 | 0.71 |
Propionaldehyde | 0.35 | 0.87 | 0.79 | 0.97 | 1.44 | 1.46 | |
Acrorein | 0.35 | 0.81 | 0.77 | 0.91 | 1.44 | 1.52 | |
iso-Butylaldehyde | 0.46 | 1.51 | 1.37 | 1.67 | 2.54 | 2.50 | |
Butylaldehyde | 0.54 | 1.77 | 1.62 | 1.96 | 3.07 | 3.04 | |
Alkane | Pentane | 0.34 | 1.24 | 1.02 | 1.19 | 1.39 | 1.10 |
Hexane | 0.48 | 2.56 | 2.03 | 2.46 | 3.00 | 2.20 | |
Heptane | 0.73 | 5.26 | 4.27 | 5.03 | 6.22 | 4.39 | |
Octane | 1.14 | 10.99 | 8.54 | 10.36 | 13.28 | 8.94 | |
Aromaten | Benzene | 0.87 | 2.76 | 2.56 | 3.00 | 4.00 | 3.74 |
Toluene | 1.33 | 5.72 | 5.31 | 6.41 | 8.54 | 7.61 | |
Ethyl Benzene | 2.09 | 11.60 | 1069 | 12.98 | 17.58 | 15.05 | |
o-Xylene | 2.52 | 13.48 | 12.53 | 15.32 | 20.79 | 18.05 | |
Chloroalkyle | Methylene Chloride | 0.41 | 0.98 | 0.94 | 1.09 | 1.48 | 1.67 |
Chloroform | 0.59 | 1.89 | 1.76 | 2.15 | 2.91 | 3.04 | |
Carbon Tetrachloride | 0.75 | 2.87 | 2.42 | 2.98 | 3.49 | 3.04 | |
1,2-Dichloroethane | 0.78 | 2.28 | 2.16 | 2.56 | 3.84 | 4.09 | |
1,2-Dichloropropane | 0.98 | 3.84 | 3.47 | 4.23 | 6.29 | 6.37 | |
Ester | Methyl formate | 0.27 | 0.51 | 0.53 | 0.57 | 0.91 | 0.94 |
Methyl acetate | 0.38 | 1.01 | 0.97 | 1.11 | 1.74 | 1.75 | |
Ethyl acetate | 0.52 | 1.99 | 1.83 | 2.15 | 3.30 | 3.16 | |
Methyl propionate | 0.57 | 1.99 | 1.83 | 2.15 | 3.30 | 3.16 | |
Butyl acetate | 1.39 | 8.78 | 7.35 | 9.44 | 14.60 | 13.88 | |
Ether | Diethyl ether | 0.33 | 1.41 | 0.98 | 1.27 | 1.45 | 1.28 |
Keton | Acetone | 0.33 | 0.89 | 0.81 | 0.96 | 1.59 | 1.66 |
Anorganisch | Water | 0.25 | 0.32 | 0.41 | 0.35 | 0.61 | 0.83 |